Analysis of cadmium in sodium hypochlorite solutions by Anodic Stripping Voltammetry test: a preliminary study

Authors

  • Charliani Menegassi Marostegan
  • Renata Grazziotin-Soares
  • Diego Machado Ardenghi
  • José Antônio Poli de Figueiredo
  • Tiago André Fontoura de Melo

DOI:

https://doi.org/10.15448/1980-6523.2017.2.27065

Keywords:

Endodontics, Cadmium, Sodium hypochlorite, Human body

Abstract

Objective: The literature reports that Cadmium (Cd) is highly toxic to human body and dental tissues. Sodium hypochlorite (NaOCl) irrigating solutions used in root canal treatment are composed of several metals. However, there is no study regarding the presence of Cd in these solutions. This study aimed to verify the existence of Cd on 2.5% NaOCl solutions proceeding from different origins, being to date the first of the kind.
Methods: Three solutions of 2.5% NaOCl from different origins were assessed in relation to the chlorine content and the presence/amount (mg/L) of cadmium by the Anodic Stripping Voltammetry (ASV) test. Oxidation-Reduction Titration (OR) method was performed to quantify the available chlorine. The types of NaOCl solutions were from: i) hand manipulated at a pharmacy, ii) industrialized and commercialized at a dental supply store and iii) industrialized and commercialized at a grocery supermarket.
Results : The ASV test showed the amount of cadmium was 0.14mg/L for solutions coming from the pharmacy and the supermarket, and 0.13 mg/L for the solution coming from the dental supply store. OR method found the following amount of available chlorine: 1.15% and 1.52% and 2.24% NaOCl for solutions proceeding from the pharmacy, dental supply store and supermarket, respectively.
Conclusion : All samples presented levels of Cd above the permissible limits stated by the legislation from where the study was conducted (0.01 mg/L).

Author Biographies

Charliani Menegassi Marostegan

São Leopoldo Mandic, Porto Alegre, Brazil

Renata Grazziotin-Soares

University of Saskatchewan, SK, Canada

Diego Machado Ardenghi

University of Saskatchewan, SK, Canada

José Antônio Poli de Figueiredo

Pontifícia Universidade Católica do Rio Grande do
Sul, Porto Alegre, Brazil

Tiago André Fontoura de Melo

Universidade Federal do Rio Grande do Sul, Porto
Alegre, Brazil

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2017-11-23

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